Slice bread into eight 3/4-inch slices. In medium bowl, beat eggs with milk, Grand Marnier, sugar, vanilla, salt and orange peel until well blended. Dip each piece of bread into liquid mixture until well saturated. Place in a flat baking dish. Pour remaining liquid over bread. Cover and refrigerate overnight.
In skillet, heat oil and saute bread until golden on both sides. Brush with butter and sprinkle with powdered sugar. Top with orange slice and serve immediately with maple syrup.
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